Volume 565
Main Index

Issues 1-2, Pages 1-303 (28 August 1998)

Editorial Pages 1-2

Reversible coordination of the high oxidation state dioxo-acetylide fragment (C5Me5)W(O)2(CCPh) to a hexaruthenium cluster frame Pages 3-10 Wen-Ji Chao, Yun Chi, Cathy Chung, Arthur J. Carty, Esther Delgado, Shie-Ming Peng, Gene-Hsiang Lee

The unusual attachment of an alkyne across the open edge of a Rh2Pd complex Pages 11-18 Geoffrey R. County, Ron S. Dickson, Gary D. Fallon

Preparation and redox properties of phosphite derivatives of R2C2Co2(CO)6−n[P(OMe)3]n (R=CF3, MeO2C) Pages 19-28 Noel W. Duffy, C. John McAdam, Brian H. Robinson, Jim Simpson

Water soluble, hydrolytically stable derivatives of the antitumor drug titanocene dichloride and binding studies with nucleotides Pages 29-35 George Mokdsi, Margaret M. Harding

Some acetylene and hydride chemistry of group 8 metal complexes with cyclopentadienyls and their analogous ligands Pages 37-48 Guochen Jia, Chak Po Lau

Reaction of ethynediyl, butadiynediyl and ethynyl iron complexes, (η5-C5R5)(CO)2Fe–(CC)n–X [X=Fe(η5-C5R5)(CO)2, H; R5=Me5, Me4Et; n=1, 2], with Fe2(CO)9 leading to polynuclear C2 and C4 complexes Pages 49-62 Munetaka Akita, Min-Chul Chung, Masako Terada, Masanori Miyauti, Masako Tanaka, Yoshihiko Moro-oka

Buta-1,2,3-trienylidene, acylvinylidene and acylalkynyl ruthenium complexes via activation of alkynes with RuCl2(dppe)2. X-ray structure of trans-[Ru(=C=CHCOCH2Ph)(Cl)(dppe)2]O3SCF3 Pages 63-73 Pierre Haquette, Daniel Touchard, Loïc Toupet, Pierre Dixneuf

Investigation of the iron–carbon bonding for alkyl, alkynyl, carbene, vinylidene, and allenylidene complexes using 57Fe Mössbauer spectroscopy Pages 75-80 Valérie Guillaume, Patrice Thominot, Françoise Coat, Alain Mari, Claude Lapinte

Mixed-metal cluster chemistry IX: alkylarylphosphine derivatives of [CpWIr3(CO)11] and X-ray crystal structure of [CpWIr3(μ-CO)3(CO)7(PMe2Ph)] Pages 81-95 Susan M. Waterman, Mark G. Humphrey, David C. R. Hockless

Parallel coordination of hydrazine to diruthenium units: synthesis and molecular structure of the cationic complexes [(η6-C6Me6)2Ru2(μ2-H)2(μ2-η1,η1-H2NNH2)]2+ and [(η6-C6Me6)2Ru2(μ2-H)(μ2-η1,η1-H2NNH2)(μ2-NH2)]2+ Pages 97-103 Manfred Jahncke, Antonia Neels, Helen Stoeckli-Evans, Georg Süss-Fink

Towards linked clusters: reactions of [Ru6(CO)17B]− with dppm and [ClAu(L–L)AuCl] (L–L=bis(diphenylphosphino)-alkanes, -ethene and -ethyne, and the crystal structure of [HRu6(CO)15(P,P′-dppm)B] (dppm=bis(diphenylphosphino)methane) Pages 105-114 Catherine E. Housecroft, Arnold L. Rheingold, Anne Waller, Glenn P. A. Yap

Mono and difunctionalisation of chiral ferrocenyl bis-acetals. X-Ray crystal structure of bis-1,1′-[(2S, 4S)-(hydroxymethyl)-2-dioxane1,3]-ferrocene Pages 115-124 Gabriel Iftime, Jean-Claude Daran, Eric Manoury, Gilbert G. A. Balavoine

Orthomanganation of arylhydrazones and related N-donor substrates Pages 125-134 Maarten B. Dinger, Lyndsay Main, Brian K. Nicholson

SnBrMe3 and dichalcogenides (ER)2 as oxidants: Synthesis of platinum(IV) complexes, and and coupling from pallada(IV)cyclopentane complexes and PdMe2(EPh){(pz)3BH} {E=O2C, S, Se; [(pz)3BH]−=tris(pyrazol-1-yl)borate} Pages 135-140 Allan J. Canty, Hong Jin

Linking of benzyne and carbon monoxide at a triruthenium centre by migratory insertion Pages 141-151 Jonathan P. H. Charmant, Helen A. A. Dickson, Nigel J. Grist, Selby A. R. Knox, A. Guy Orpen, Kathryn Saynor, Josep M. Viñas

Vinylidene complexes of osmium(0) derived from 1-naphthyl- or 2-naphthyl-carbyne complexes by hydride addition to the naphthyl substituents. The crystal structure of Os(=C=C10H8)(CO)2(PPh3)2 Pages 153-158 Lisa-J. Baker, Clifton E. F. Rickard, Warren R. Roper, Scott D. Woodgate, L. James Wright

Silsesquioxanes: Part I: A key intermediate in the building of molecular composite materials Pages 159-164 Arthur Provatas, Martin Luft, Jun C. Mu, Alan H. White, Jani G. Matisons, Brian W. Skelton

Synthesis and reaction chemistry of mixed ligand methylpalladium–carbene complexes Pages 165-178 David S. McGuinness, Melinda J. Green, Kingsley J. Cavell, Brian W. Skelton, Allan H. White

Use of metal carbonyls in the formation of [H5O2+·15-crown-5][MOCl4(H2O)-], (M=Mo, W), and a second sphere coordination complex in [mer-CrCl3(H2O)3·15-crown-5] Pages 179-186 Peter C. Junk, Jerry L. Atwood

Attachment of cyanometal units to the Fe4S4 cluster Pages 187-192 Nianyong Zhu, Ralf Appelt, Heinrich Vahrenkamp

High nuclearity ruthenium carbonyl cluster chemistry VII. Synthesis, NMR studies, electrochemistry and X-ray crystal structure of [PPN] [Ru8(μ8-P)(CO)22] Pages 193-200 Marie P. Cifuentes, Susan M. Waterman, Mark G. Humphrey, Graham A. Heath, Brian W. Skelton, Allan H. White, M. P. Seneka Perera, Michael L. Williams

Organolanthanoids XXIII complexes of tris(cyclopentadienyl)lanthanoids with tertiary phosphine oxides and the X-ray crystal structures of [YbCp3(OPPh3)] and [NdCp3(OPBun3)] Pages 201-210 Glen B. Deacon, Gary D. Fallon, Craig M. Forsyth, Bryan M. Gatehouse, Peter C. Junk, Anna Philosof, Paul A. White

Perspectives in syntheses, structures and bonding of acetylide-containing clusters of group 11 metals Pages 211-216 Omar M. Abu-Salah

Five-coordinate hydrogen in hydrido rhodium cluster compounds: A theoretical analysis Pages 217-224 Régis Gautier, Jean-François Halet

1,3,5-Trimethyl-1,3,5-triazacyclohexane tricarbonyl complexes of Mo and W as sources of the fac-M(CO)3 fragment. Mild syntheses of fac-[M(CO)3(CH3CN)3] (M=Mo, W), [W(CO)3(PR3)3], [W(CO)(alkyne)3] and [W(CO)3(π-arene)] complexes Pages 225-230 Murray V. Baker, Michael R. North

A series of triisopropylstibine ruthenium and osmium complexes including the X-ray crystal structure of [RuCl2(CO)(SbiPr3)3] and [RuCl2(=C=C=CPh2)(CO)(SbiPr3)2] Pages 231-241 H. Werner, C. Grünwald, P. Steinert, O. Gevert, J. Wolf

Diferrocenyltriphosphines 1: five-coordinate ruthenium complexes Pages 243-258 Ian R. Butler, Ulrich Griesbach, Piero Zanello, Marco Fontani, David Hibbs, Michael B. Hursthouse, K. L. M. Abdul Malik

Reactions of metalloalkynes 3. Facile synthesis of pentanuclear ruthenium clusters. X-ray structures of [Ru5(μ5-CC)(η-C5H4R)2(dppm)(μ2-CO)2(CO)7] (R=H, CH3) Pages 259-265 Lindsay T. Byrne, Christopher S. Griffith, James P. Hos, George A. Koutsantonis, Brian W. Skelton, Allan H. White

Synthesis and X-ray structure of Ru3(CO)6(μ2-CO)(μ2-AsPh2)(μ-O=C---C12H17), a first example of a CO insertion reaction to a cluster-bound hydrocarbon Pages 267-270 Omar bin Shawkataly, K. Puvanesvary, H. K. Fun, K. Sivakumar

Organometallic clusters: What is an appropriate DFT treatment? Pages 271-277 Michael J. Liddell

1,6-Bis(trimethylsilyl)hexa-1,3,5-triyne as a precursor to ruthenium clusters containing highly ethynylated ligands Pages 279-282 Paul J. Low, Gary D. Enright, Arthur J. Carty

The preparation of mixed ligand ruthenocenes containing bulky cyclopentadienyl ligands. Crystal structures of pentaphenylruthenocene, [Ru(η5-C5Ph5)(η5-C5H5)], pentaparatolylruthenocene, [Ru{η5-C5(p-MeC6H4)5}(η5-C5H5)] and pentaphenylpentamethylruthenocene, [Ru(η5-C5Ph5)(η5-C5Me5)] Pages 283-296 C. U. Beck, L. D. Field, T. W. Hambley, P. A. Humphrey, A. F. Masters, P. Turner

Index Page 297

Index Pages 299-303